2-propyl nitrate T dependent cross-sections ((CH3)2CHONO2) Taken from the MPI-Mainz Spectral Atlas: http://www.atmosphere.mpg.de/enid/2295 From IUPAC 2005 recommendation http://www.iupac-kinetic.ch.cam.ac.uk/ Taken from: 1. J. M. Roberts and R. W. Fajer, Environ. Sci. Technol. 23, 945 (1989). 2. M. P. Turberg, D. M. Giolando, C. Tilt, T. Soper, S. Mason, M. Davies, P. Klingensmith, and G. A. Takacs, J. Photochem. Photobiol. A51, 281 (1990). 3. K. C. Clemitshaw, J. Williams, O. V. Rattigan, D. E. Shallcross, K. S. Law, and R. A. Cox, J. Photochem. Photobiol. A: Chemistry 102, 117 (1997). 4. R. K. Talukdar, J. B. Burkholder, M. Hunter, M. K. Giles, J. M. Roberts, and A. R. Ravishankara, J. Chem. Soc. Faraday Trans. 93, 2797 (1997). Quantum Yield There are no data on either the products of photodissociation or the quantum yields. However, the quantum yields for photodissociation of both ethyl and methyl nitrate to form NO2 have been shown to be unity at 308 nm and 248 nm, see IUPAC datasheets for these RONO2 species Equation: ln (sigma (T)) - ln (sigma (298 K)) = B(T-(298)) wavelength (nm) sigma (298K) B(K-1) 185 1.79E-17 -0.009 188 1.81E-17 -0.009 190 1.79E-17 -0.009 195 1.61E-17 -0.009 200 1.26E-17 -0.009 205 8.67E-18 -0.009 210 4.98E-18 -0.009 215 2.47E-18 -0.009 220 1.25E-18 -0.009 225 6.20E-19 -0.009 230 3.40E-19 -0.009 235 1.80E-19 -0.009 240 1.10E-19 0.0028 245 7.00E-20 0.0027 250 5.40E-20 0.0025 255 4.90E-20 0.0025 260 4.60E-20 0.0026 265 4.30E-20 0.0028 270 3.90E-20 0.0031 275 3.40E-20 0.0033 280 2.80E-20 0.0036 285 2.20E-20 0.004 290 1.60E-20 0.0044 295 1.20E-20 0.0048 300 7.80E-21 0.0054 305 5.00E-21 0.0061 310 2.90E-21 0.0069 315 1.70E-21 0.0081 320 8.50E-22 0.0094 325 4.40E-22 0.0111 330 2.20E-22 0.0119 335 1.10E-22 0.014 340 5.30E-23 0.0139 345 1.80E-23 -0.009 350 8.00E-24 -0.009 355 2.90E-24 -0.009 360 1.80E-24 -0.009